why is phosphate dosing done in a boiler? - quora

Why is phosphate dosing done in a boiler? - Quora

Phosphate is doing interesting job in Boiler. It works as an anti-scalant since phosphate react with calcium hardness to create suspended solids (which is easier to discharge via blowdown) in order to prevent any calcium carbonate (CaCO3) /calcium

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using of congruent phosphate as equilibrium phosphate

Using of congruent phosphate as equilibrium phosphate

Using of congruent phosphate as equilibrium phosphate boilers water treatment I. M. Baghni & A. I. Zwebek Engineering Academy, Tajoura, Libya Abstract Coordinated and congruent phosphates boiler water treatment has been used for more than forty years. They are very effective scale inhibitors for low and high pressure boilers.

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chapter 12 boiler deposits: occurence and control - suez

Chapter 12 Boiler Deposits: Occurence And Control - SUEZ

To minimize the iron deposition in high-pressure (1000-1750 psig) boilers, specific polymers have been designed to disperse the iron and keep it in the bulk water. As with phosphate precipitation and chelant control programs, the use of these polymers with coordinated …

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the international association for the properties of water

The International Association for the Properties of Water

Phosphate and caustic treatments are common forms of chemical treatments for drum boilers of conventional fossil plants and for the multi-pressure drums in combined cycle/HRSG plants. They are the subject of this part of the suite of IAPWS Technical Guidance Documents [2-4, 13, 16]. The purpose of this document is to provide guidance

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disadvantages of trisodium phosphate dosing in high

disadvantages of trisodium phosphate dosing in high

3.How about the quality of disadvantages of trisodium phosphate dosing in high pressure boiler ? Our industrial steam boiler manufactured strictly according to national and international standard. our products have approved ASME, IBR, ISO9001-2008, etc.

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(pdf) using of congruent phosphate as equilibrium

(PDF) Using of congruent phosphate as equilibrium

Jonas, O. and Layton, K.F., Phosphate boiler water treatment for high pressure boilers, Proceeding of Second Fossil Plant Cycle Chemistry Conference, Seattle, GS-6166, Aug(1988).

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plant service bulletin: boiler water phosphate chemistry

Plant Service Bulletin: Boiler Water Phosphate Chemistry

The coordinated phosphate treatment uses the feed of sodium phosphates in maintaining the boiler water pH. One of the disadvantages of this treatment is that, on high-pressure drum type units, the detectable concentration of phosphate in the bulk boiler water can decrease with increasing load and pressure, and

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ph and phosphate concentration in bfw and steam drum

Ph And Phosphate Concentration In Bfw And Steam Drum

Ph And Phosphate Concentration In Bfw And Steam Drum - posted in Industrial Professionals: Boiler feed water (BFW) pH is to be maintained in the range of 8.0 to 9.5(guidelines) where as in steam drum pH maintaining guidelines is in the range of 9.5 to 11.0. Pressure of steam drum is 34 barg. Since dosing of PO4 (Trisodium phosphate is dosing in steam drum) cannot be a controlling media

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boiler water treatment - hartford steam boiler inspection

Boiler Water Treatment - Hartford Steam Boiler Inspection

Boiler Water Treatment Phosphate compounds are common additives for boiler water treatment. Phosphate compounds react with any remaining hard water compounds to create a soft sludge that is eliminated through blowdown. Trisodium phosphate is the most common compound for lower pressure boilers. Phosphates also scavenge (or remove) any remaining

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***3b1 chapter 10 internal h2o treatment for boilers

***3B1 Chapter 10 Internal H2O Treatment for Boilers

In more critical, high-pressure boilers, the most common internal treatment, in addition to scale prevention, involves the use of a phosphate program. There are three such programs, called 1. simplified phosphate 2. coordinated phosphate 3. concurrent phosphate 4. congruent phosphate 5. equilibrium phosphate a. 1,3,5 b. 2,4,5 c. 1,2,3 d. 2,3,4

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chapter 39 boiler water treatment


boiler water, calcium will preferentially precipitate as the phosphate before pre-cipitating as the carbonate, and calcium phosphate becomes the most prominent feature of the deposit. At the high temperatures found in a boiler, deposits are a serious problem, causing poor heat transfer and a potential for boiler tube failure. In low-pressure

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boiler water - wikipedia

Boiler water - Wikipedia

High pressure boilers using demineralized water are most vulnerable to caustic corrosion. Hydrolysis of trisodium phosphate is a pH buffer in equilibrium with disodium phosphate and sodium hydroxide. Chelants. Chelants like ethylenediaminetetraacetic acid (EDTA) or nitrilotriacetic acid (NTA) form complex ions with calcium and magnesium.

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table 7-4.trisodium phosphate dosage for natural

Table 7-4.Trisodium Phosphate Dosage For Natural

The procedures for determining the chemical treatment Table 7-4.—Trisodium Phosphate Dosage For Natural Circulation Auxiliary Boilers (Trisodium Pbosphate, Dodecahydrate, Na 3 PO 4 12H 2 0) Boiler water Alkalinity epm (meg/L) 0.1 0.095 X = 0.2 0.090 X = 0.3 0.085 X = 0.4 0.080 X = 0.5 0.075 X = 0.6 0.070 X = 0.7 0.065 X = 0.8 0.060 X = 0.9 0

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high-pressure steam cycle and boiler water treatment

High-Pressure Steam Cycle and Boiler Water Treatment

HP and LP Differences • High pressure – Makeup water is very pure and corrosive • Low level of dissolved solids – Based on coordination of phosphate and pH so that no free caustic exists – Lower chemical treatment levels – Lower tolerances for variations in chemical levels and TDS – Production of high purity steam • Low pressure – Based on phosphate precipitation

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sodium phosphate – water technology report

sodium phosphate – Water Technology Report

Apr 27, 2015 · These include sodium phosphate, chelating agents like EDTA, and synthetic polymers. Two forms of sodium phosphate find application in low and medium pressure boilers; disodium phosphate (NaHPO4 having a 49% P2O5 content) and sodium metaphosphate (NaPO3 having a 69% P2O5 content). Both react under boiler conditions to produce orthophosphate (o-PO4).

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chapter 11- preboiler & industrial boiler corrosion control

Chapter 11- Preboiler & Industrial Boiler Corrosion Control

Phosphate buffers the boiler water, reducing the chance of large pH changes due to the development of high caustic concentrations. Excess caustic combines with disodium phosphate and forms trisodium phosphate. Sufficient disodium phosphate must be available to combine with all of the free caustic in order to form trisodium phosphate.

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phosphate hideout

Phosphate Hideout

Phosphate hideout usually results in an increase of PO4 concentration and a decrease of pH during load reduction and in an increase of pH and decrease of PO4 concentration during the load increases. The severity of phosphate hideout is boiler, heat flux, temperature, pressure, and boiler cleanliness specific.

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trisodium phosphate - an overview | sciencedirect topics

Trisodium Phosphate - an overview | ScienceDirect Topics

Pao and Davis (1999) found that an 8-min treatment with 2% trisodium phosphate did not reduce the level of E. coli on orange surfaces any more than water alone. Pao et al . ( 1999 , 2000 ) demonstrated that alkaline washes with sodium and potassium hydroxide reduced E. coli on the surface of oranges, and suggested that high pH waxes used on the

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boiler water treatment - lenntech

Boiler water treatment - Lenntech

The treatment and conditioning of boiler feed water must satisfy three main objectives:. Continuous heat exchange; Corrosion protection; Production of high quality steam; External treatment is the reduction or removal of impurities from water outside the boiler. In general, external treatment is used when the amount of one or more of the feed water impurities is too high to be tolerated by the

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chemical treatment requirements for steam and hot water

Chemical Treatment Requirements for Steam and Hot Water

Jun 12, 2017 · Above the equilibrium line, free caustic soda exists with trisodium phosphate. Below the curve, no free OH alkalinity is present. Coordinated phosphate programs are used in high pressure boilers operating in the 1000 to 1500 psig range. Demineralized feedwater is required to maintain an alkalinity-free makeup.

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